Can low-valent silicon compounds be better transition metal ligands than phosphines and NHCs?

Author:

Benedek Zsolt1234,Szilvási Tibor1234

Affiliation:

1. Department of Inorganic and Analytical Chemistry

2. Budapest University of Technology and Economics

3. 1111 Budapest

4. Hungary

Abstract

We investigated the potential application of low-valent silicon compounds as transition metal ligands by computing the most important ligand properties and compared them to the generally used carbene and phosphine ligands.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference101 articles.

1. Transition Metals for Organic Syntheses, ed. M. Beller and C. Bolm, Wiley, 2004

2. Applications of Transition Metal Catalysis in Drug Discovery and Development, ed. M. L. Crawley and B. M.Trost, Wiley, 2012

3. Ligand electronic effects in homogeneous catalysis using transition metal complexes of phosphine ligands, ed. M. L. Clarke and J. J. R. Frew, RSC Publishing, 2009

4. Phosphorus(III) ligands in homogeneous catalysis: Design and synthesis, ed. P. C. J. Kamer and P. W. N. M. van Leeuwen, Wiley, 2012

5. Homogeneous Catalysis with Metal Phosphine Complexes, ed. L. M. Pignolet, Springer, 2013

Cited by 111 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3