Electrochemical ammonia synthesis under ambient conditions using TM-embedded porphine-fused sheets as single-atom catalysts

Author:

Yao Ying12ORCID,Lv Sheng-Yao12ORCID,Li Guoliang1ORCID,Yang Li-Ming2

Affiliation:

1. Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, School of Chemistry, South China Normal University, Guangzhou 510006, China

2. Key Laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education, Hubei Key Laboratory of Bioinorganic Chemistry and Materia Medica, Hubei Key Laboratory of Materials Chemistry and Service Failure, Hubei Engineering Research Center for Biomaterials and Medical Protective Materials, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, China

Abstract

Thirty transition metal atoms were embedded into porphine-fused sheets (TM-Por) to form single-atom catalysts for eNRR under ambient conditions. Three TM-Por (TM = Mo, Tc, Nb) catalysts were predicted with excellent catalytic performance.

Funder

National Natural Science Foundation of China

Huazhong University of Science and Technology

Fundamental Research Funds for the Central Universities

Basic and Applied Basic Research Foundation of Guangdong Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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