Mechanistic exploration of syngas conversion at the interface of graphene/Cu(111): identifying the effect of promoted electron transfer on the product selectivity

Author:

Wei Zhongzeng1,Bai Bing1,Bai Hui1ORCID,Duan Yongliang2,Yang Mingxue1,Cao Haojie1,Zuo Zhijun1,Zuo Jianping3,Wang Qiang4ORCID,Huang Wei1ORCID

Affiliation:

1. State Key Laboratory of Clean and Efficient Coal Utilization, College of Chemical Engineering and Technology, Taiyuan University of Technology, Taiyuan 030024, Shanxi, China

2. National Energy Ningxia Coal Industry Group Coal Chemical Industry Technology Research Institute, Yinchuan 750411, Ningxia, China

3. School of Mechanics and Civil Engineering, China University of Mining and Technology, Beijing 100083, China

4. National Key Laboratory of High Efficiency and Low Carbon Utilization of Coal, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China

Abstract

The graphene/Cu(111) interface modulates the product selectivity of syngas conversion by promoting the electron transfer in the confined space.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Shanxi Province

Science and Technology Innovation Group of Shanxi Province

Taiyuan University of Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

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