The synthesis, characterization, and theoretical analysis of novel Si-substituted silylethyl derivatives of 2-mercaptobenzoxazole and 2-mercaptobenzothiazole

Author:

Trofimova Olga1234ORCID,Grebneva Ekaterina1234,Bolgova Yuliya1234ORCID,Belogolova Elena1234ORCID,Emel’yanov Artem1234,Albanov Alexander1234,Borodina Tat’yana1234,Ivanova Anastasiya1234,Korzhova Svetlana1234,Pozdnyakov Alexander1234

Affiliation:

1. A. E. Favorsky Irkutsk Institute of Chemistry

2. Siberian Branch of the Russian Academy Sciences

3. 664033 Irkutsk

4. Russian Federation

Abstract

Trifluorosilylethyl derivatives of 2-mercaptobenzoxazole and 2-mercaptobenzothiazole C6H4NYCS(CH2)2SiF3 (Y = O, S) have been synthesized in order to study the intramolecular N → Si interaction in compounds with the SiCCSCN fragment.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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