Synthesis and structure of thienyl Fischer carbene complexes of PtII for application in alkyne hydrosilylation
Author:
Affiliation:
1. Department of Chemistry
2. University of Pretoria
3. Hatfield 0028
4. South Africa
5. Laboratory of Inorganic Chemistry
6. Environmental and Chemical Engineering
7. University of Oulu
8. 90014 Oulu
9. Finland
Abstract
Efficient alkyne hydrosilylation mediated by well-defined platinum(ii) bis(ethoxycarbene) complexes of the Fischer-type prepared by facile transmetallation.
Funder
National Research Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2021/NJ/D1NJ00791B
Reference55 articles.
1. Über Die Hydrazin-Carbylamin-Komplexe des Platins
2. Chelative addition of hydrazines to coordinated isocyanides. Structure of Chugaev's red salt
3. The reactions of isocyanide complexes of platinum(II): a convenient route to carbene complexes
4. Cationic acetylenic platinum(II) compounds and their derivatives. II. Acetylene and vinyl ether complexes
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1. Cyclobutadiene platinum complex as a new type of precatalyst for hydrosilylation of alkenes and alkynes;Applied Organometallic Chemistry;2023-01-06
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3. Roles played by carbene substituents during ligand transfer reactions between tungsten fischer carbene complexes and [Pt(COD)Cl2];Journal of Organometallic Chemistry;2021-12
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