Electrochemically driven, cobalt–carbon bond-mediated direct intramolecular cyclic and acyclic perfluoroalkylation of (hetero)arenes using X(CF2)4X-Reference-Cited by-同舟云学术

Electrochemically driven, cobalt–carbon bond-mediated direct intramolecular cyclic and acyclic perfluoroalkylation of (hetero)arenes using X(CF2)4X

Published:2020 Issue:42 Volume:10 Page:24862-24866
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Cui Luxia¹²³⁴,Ono Toshikazu¹²³⁴⁵^ORCID,Hossain Md. Jakir¹²³⁴,Hisaeda Yoshio¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry

2. Graduate School of Engineering

3. Kyushu University 744 Motooka

4. Japan

5. Center for Molecular Systems (CMS)

Abstract

A proof-of-concept for synthetically challenging cyclic and acyclic perfluoroalkylation of (hetero)arenes driven by the valence change of a cobalt catalyst with X(CF₂)₄X is demonstrated.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/RA/D0RA05295G

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