Multiple coupling of silanes with imido complexes of Mo-Reference-Cited by-同舟云学术

Multiple coupling of silanes with imido complexes of Mo

Published:2014 Issue:22 Volume:43 Page:8446-8453
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Khalimon Andrey Y.¹²³,McLeod Nicolas A.¹²³,Ignatov Stanislav K.¹⁴⁵,Okhapkin Andrey I.¹⁴⁵,Kuzmina Lyudmila G.⁶⁷,Howard Judith A. K.⁸⁹¹⁰,Nikonov Georgii I.¹²³

Affiliation:

1. Chemistry Department

2. Brock University

3. St. Catharines, Canada

4. N. I. Lobachevsky State University of Nizhny Novgorod

5. Nizhny Novgorod, Russia

6. N. S. Kurnakov Institute of General and Inorganic Chemistry

7. Moscow, Russia

8. Department of Chemistry

9. University of Durham

10. Durham, UK

Abstract

Coupling of (^tBuN)₂Mo(PMe₃)(L) (L = PMe₂, C₂H₄) with PhSiH₃results in a product of triple silane addition, (^tBuN){μ-^tBuN(SiHPh)₂}Mo(H)(SiH₂Ph)(PMe₃)₂(3), formation of which proceedsviaa series of silanimine and Si–H⋯Mo agostic species.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT00154K

Reference48 articles.

1. Hydrosilylation, Advances in Silicon Science , ed. B. Marciniec , Springer , 2009

2. R. Noyori , Asymmetric Catalysis in Organic Synthesis , John Wiley & Sons , New York , 1994

3. Catalytic Asymmetric Synthesis , ed. I. Ojima , Wiley , New York , 3rd edn, 2010

4. H. Brunner and W.Zettimeier , Handbook of Enantioselective Catalysis with Transition Metal Compounds , VCH , Weinheim , 1993

Cited by 4 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Cyclic and Non-Cyclic Pi Complexes of Molybdenum;Reference Module in Chemistry, Molecular Sciences and Chemical Engineering;2021

2. Manganese Silyl Dihydride Complexes: A Spectroscopic, Crystallographic, and Computational Study of Nonclassical Silicate and Hydrosilane Hydride Isomers;Organometallics;2019-05-24

3. Reactivity of Ln(II) Complexes Supported by (C5H4Me)1– Ligands with THF and PhSiH3: Isolation of Ring-Opened, Bridging Alkoxyalkyl, Hydride, and Silyl Products;Organometallics;2018-08-31

4. Alternative mechanism of silane addition to the imido complex (tBuN=)2Mo(PMe3)2. A quantum chemical study;Computational and Theoretical Chemistry;2015-12