Reactions of a distonic peroxyl radical anion influenced by SOMO–HOMO conversion: an example of anion-directed channel switching-Reference-Cited by-同舟云学术

Reactions of a distonic peroxyl radical anion influenced by SOMO–HOMO conversion: an example of anion-directed channel switching

Published:2020 Issue:4 Volume:22 Page:2130-2141
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

So Sui¹²³,Kirk Benjamin B.⁴⁵³,Wille Uta⁶²³^ORCID,Trevitt Adam J.⁴⁵³^ORCID,Blanksby Stephen J.⁷⁸⁹³^ORCID,da Silva Gabriel¹²³^ORCID

Affiliation:

1. Department of Chemical Engineering

2. The University of Melbourne

3. Australia

4. School of Chemistry

5. University of Wollongong

6. School of Chemistry and Bio21 Institute

7. Central Analytical Research Facility

8. Institute for Future Environments

9. Queensland University of Technology

Abstract

Deprotonation of a remote site in a peroxyl radical energetically buries the singly occupied molecular orbital, suppressing radical-driven oxidation and promoting reactions involving the anion site.

Funder

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CP/C9CP05989J

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2. Interplay between magnetism and conductivity derived from spin-polarized donor radicals

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4. Hydrogen-Bonding-Assisted Self-Doping in Tetrathiafulvalene (TTF) Conductor

5. Origin and Scope of Long-Range Stabilizing Interactions and Associated SOMO–HOMO Conversion in Distonic Radical Anions

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