Manganese catalyzed C–H functionalization of indoles with alkynes to synthesize bis/trisubstituted indolylalkenes and carbazoles: the acid is the key to control selectivity

Author:

Shi Lijun12345,Zhong Xiang678910,She Houde12345,Lei Ziqiang12345,Li Fuwei678910

Affiliation:

1. Key Laboratory of Eco-Environment-Related Polymer Materials of Ministry of Education

2. College of Chemistry and Chemical Engineering

3. Northwest Normal University

4. Lanzhou 730070

5. China

6. State Key Laboratory for Oxo Synthesis and Selective Oxidation

7. Suzhou Research Institute of LICP

8. Lanzhou Institute of Chemical Physics (LICP)

9. Chinese Academy of Sciences

10. Lanzhou

Abstract

The Mn-catalyzed C–H alkenylations of indole with terminal- and/or internal-alkynes have been developed to selectively yield indolylalkene and carbazole.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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