Reactions catalyzed by a binuclear copper complex: selective oxidation of alkenes to carbonyls with O2
Author:
Affiliation:
1. Key Laboratory of Applied Surface and Colloid Chemistry
2. Ministry of Education
3. Department of Chemistry & Chemical Engineering
4. Shaanxi Normal University
5. Xi'an
Abstract
A binuclear copper complex bearing a simple salicylate ligand catalyses the efficient cleavage of styrenes into ketones and aldehydes with O2 as the oxidant. The reaction works under an atmosphere of O2 (balloon) with 0.5 mol% of catalyst and could be performed on a gram scale, providing an alternative to ozonolysis.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2017/CY/C7CY01757J
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