N–B dative bond-induced [3.3.0] bicyclic boronate-tethered exo-selective intramolecular Diels

N–B dative bond-induced [3.3.0] bicyclic boronate-tethered exo-selective intramolecular Diels–Alder reaction

Published:2015 Issue:26 Volume:13 Page:7136-7139
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Feng Chao¹²³⁴⁵,Wang Hong¹²³⁴⁵,Xu Liang¹²³⁴⁵,Li Pengfei¹²³⁴⁵

Affiliation:

1. Centre for Organic Chemistry

2. Frontier Institute of Science and Technology (FIST)

3. Xi'an Jiaotong University

4. Xi'an

5. China

Abstract

We report herein a highly exo-selective intramolecular Diels–Alder reaction of alkenyl boronates which employs an N–B dative bond-involved bicyclic rigid tether.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/OB/C5OB00917K

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