NIR bacteriochlorin chromophores accessed by Heck and Sonogashira cross-coupling reactions on a tetrabromobacteriochlorin derivative-Reference-Cited by-同舟云学术

NIR bacteriochlorin chromophores accessed by Heck and Sonogashira cross-coupling reactions on a tetrabromobacteriochlorin derivative

Published:2016 Issue:4 Volume:14 Page:1402-1412
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

de Assis Francisco F.¹²³⁴,Ferreira Marco A. B.¹²³⁴,Brocksom Timothy J.¹²³⁴,de Oliveira Kleber T.¹²³⁴

Affiliation:

1. Departamento de Química

2. Universidade Federal de São Carlos – UFSCar

3. 13565-905 São Carlos

4. Brazil

Abstract

The synthesis of a new tetrabromobacteriochlorin BCBr4 is reported. Pd cross-coupling reactions yielded tetra-coupled products with a significant red shift in the UV-Vis bands.

Funder

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/OB/C5OB02228B

Reference40 articles.

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2. De Novo Synthesis of Stable Tetrahydroporphyrinic Macrocycles: Bacteriochlorins and a Tetradehydrocorrin

3. Photophysical Properties and Electronic Structure of Stable, Tunable Synthetic Bacteriochlorins: Extending the Features of Native Photosynthetic Pigments

4. Expanded Scope of Synthetic Bacteriochlorins via Improved Acid Catalysis Conditions and Diverse Dihydrodipyrrin-Acetals

5. In Vitro Photodynamic Therapy and Quantitative Structure−Activity Relationship Studies with Stable Synthetic Near-Infrared-Absorbing Bacteriochlorin Photosensitizers

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