Photoinduced molecular transformations. Part 144. One-carbon intercalation of γ- and δ-lactones involving the β-scission of alkoxyl radicals as the key step: synthesis of δ- and Îµ-lactones with α-substituents-Reference-Cited by-同舟云学术

Photoinduced molecular transformations. Part 144. One-carbon intercalation of γ- and δ-lactones involving the β-scission of alkoxyl radicals as the key step: synthesis of δ- and Îµ-lactones with α-substituents

Published:1993 Issue:23 Volume: Page:3007-3010
ISSN:0300-922X
Container-title:J. Chem. Soc., Perkin Trans. 1
language:en
Short-container-title:J. Chem. Soc., Perkin Trans. 1

Author:

Kobayashi Kazuhiro,Minakawa Hiroki,Sakurai Hideo,Kujime Sachiko,Suginome Hiroshi

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/1993/P1/P19930003007

Reference29 articles.

1. Photoinduced molecular transformations. Part 143. (2 + 2) Photoaddition of 3-hydroxy-1-benzopyran-2-one, 3-benzyloxycarbonyloxy-1-benzopyran-2-one, and their 8-methoxy derivatives, with alkenes and formation of 1,2-disubstituted 1,2-dihydrofuro[2,3-c][1]benzopyran-4-ones by way of β-scission of cyclobutanoxyl radicals generated from the resulting [2 + 2] photoadducts

2. Photo-induced transformations. Part 79. On the mechanism of the formation of oxa steroids via photo- and thermally-induced rearrangement of 3-hydroxy-Δ5-steroid hypoiodites in the presence of mercury(II) oxide and iodine. An oxygen-18 labelling study.

3. Photoinduced transformations. 76. A four-step substitution of a carbonyl group of steroidal ketones by an oxygen atom. A new method for the synthesis of cyclic ethers

4. New general synthesis of medium ring-lactones a regioselective β-scission of alkoxyl radicals generated from catacondensed lactols

5. Photoinduced molecular transformations. Part 107. A versatile substitution of a carbonyl group of steroidal ketones by a heteroatom. The synthesis of aza-, oxa-, thia-, selena-, and tellurasteroids

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