Relativistic modulation of supramolecular halogen/copper interactions and phosphorescence in Cu(<scp>i</scp>) pyrazolate cyclotrimers-Reference-Cited by-同舟云学术

Relativistic modulation of supramolecular halogen/copper interactions and phosphorescence in Cu(i) pyrazolate cyclotrimers

Published:2023 Issue:13 Volume:52 Page:3964-3970
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Lu Zhou¹^ORCID,Vanga Mukundam²^ORCID,Li Shan¹^ORCID,Adebanjo Joseph O.¹^ORCID,Patterson Monika R.²^ORCID,Dias H. V. Rasika²^ORCID,Omary Mohammad A.¹^ORCID

Affiliation:

1. Department of Chemistry, University of North Texas, 1155 Union Circle #305070, Denton, Texas 76203, USA

2. Department of Chemistry and Biochemistry, The University of Texas at Arlington, Arlington, Texas 76019, USA

Abstract

Cu3[4-I-3,5-(CF3)2Pz]3 exhibits stronger supramolecular Cu3⋯halogen interactions vs. its 4-Br/4-Cl analogues, double- vs. single-capped; this relativistic enhancement yet results in quenched phosphorescence.

Funder

National Science Foundation

Welch Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D2DT03725D

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4. Trinuclear Copper(I) and Silver(I) Adducts of 4-Chloro-3,5-bis(trifluoromethyl)pyrazolate and 4-Bromo-3,5-bis(trifluoromethyl)pyrazolate

5. Silver(I) and Copper(I) Adducts of a Tris(pyrazolyl)borate Decorated with Nine Trifluoromethyl Groups

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