Phosphinite-functionalized silica and hexagonal mesoporous silica containing palladium nanoparticles in Heck coupling reaction: synthesis, characterization, and catalytic activity

Author:

Farjadian Fatemeh12345,Hosseini Majid6789,Ghasemi Soheila51011124,Tamami Bahman51011124

Affiliation:

1. Pharmaceutical Science Research Center

2. Shiraz University of Medical Sciences

3. Shiraz

4. Iran

5. Department of Chemistry

6. Department of Chemical & Biomolecular Engineering

7. The University of Akron

8. Akron

9. USA

10. College of Sciences

11. Shiraz University

12. Shiraz 71454

Abstract

The preparation of phosphinite-functionalized silica and hexagonal mesoporous silica containing palladium nanoparticles is described. These catalysts were explored as heterogeneous catalytic systems in HCR with different substrates.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference39 articles.

1. H. Hudson , Primary, secondary and tertiary phosphines, polyphosphines and heterocyclic organophosphorus(iii) compounds, Wiley, New York, 1990, pp. 386–472

2. J. A. Gillespie , E.Zuidema, P. W.van Leeuwen and P. C.Kamer, Phosphorus(iii) Ligands in Homogeneous Catalysis: Design and Synthesis, 2012, pp. 1–26

3. Secondary phosphine oxides: Versatile ligands in transition metal-catalyzed cross-coupling reactions

4. Generation of Tertiary Phosphine-Coordinated Pd(0) Species from Pd(OAc)2in the Catalytic Heck Reaction

5. Orthopalladated triaryl phosphite complexes as highly active catalysts in biaryl coupling reactions

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