The electrooxidation-induced structural changes of gold di-superatomic molecules: Au23vs. Au25-Reference-Cited by-同舟云学术

The electrooxidation-induced structural changes of gold di-superatomic molecules: Au23vs. Au25

Published:2016 Issue:6 Volume:18 Page:4822-4827
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Matsuo Shota¹²³⁴⁵,Yamazoe Seiji¹²³⁴⁵,Goh Jing-Qiang⁶⁷⁸⁹¹⁰,Akola Jaakko⁶⁷⁸⁹¹⁰,Tsukuda Tatsuya¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. School of Science

3. The University of Tokyo

4. Tokyo 113-0033

5. Japan

6. Department of Physics

7. Tampere University of Technology

8. FI-33101 Tampere

9. Finland

10. COMP Centre of Excellence

Abstract

Face-sharing bi-icosahedral Au₂₃ core of Au₃₈(SC₂H₄Ph)₂₄ retained its structure, whereas vertex-sharing bi-icosahedral Au₂₅ core of [Au₂₅(PPh₃)₁₀(SC₂H₄Ph)₅Cl₂]²⁺ underwent irreversible structural change upon electrooxidation.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CP/C5CP06969F

Reference40 articles.

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2. Crystal Structure of the Gold Nanoparticle [N(C8H17)4][Au25(SCH2CH2Ph)18]

3. Correlating the Crystal Structure of A Thiol-Protected Au25 Cluster and Optical Properties

4. HCl-Induced Nuclearity Convergence in Diphosphine-Protected Ultrasmall Gold Clusters: A Novel Synthetic Route to “Magic-Number” Au13 Clusters

5. Au19 Nanocluster Featuring a V-Shaped Alkynyl–Gold Motif

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