An artificial metalloenzyme that can oxidize water photocatalytically: design, synthesis, and characterization

Author:

Polanco Ehider A.1,Opdam Laura V.1,Passerini Leonardo2,Huber Martina2ORCID,Bonnet Sylvestre1,Pandit Anjali1ORCID

Affiliation:

1. Leiden Institute of Chemistry, Leiden University, Einsteinweg 55, 2333 CC Leiden, The Netherlands

2. Department of Physics, Huygens-Kamerlingh Onnes Laboratory, Leiden University, Niels Bohrweg 2, 2333 CA, Leiden, The Netherlands

Abstract

A protein-based catalyst for photoactivated water oxidation was successfully constructed from CoSalen bound to cytochrome b5. The protein scaffold prevents the formation of large CoOx nanoparticles and strongly improves catalyst solubility.

Publisher

Royal Society of Chemistry (RSC)

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