Diiron(ii) pentacarbonyl complexes as CO-releasing molecules: their synthesis, characterization, CO-releasing behaviour and biocompatibility-Reference-Cited by-同舟云学术

Diiron(ii) pentacarbonyl complexes as CO-releasing molecules: their synthesis, characterization, CO-releasing behaviour and biocompatibility

Published:2019 Issue:2 Volume:48 Page:468-477
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Xiao Zhiyin¹²³⁴⁵^ORCID,Jiang Ran⁶⁷⁸⁵,Jin Jing⁹¹⁰⁴⁵,Yang Xiuqin⁶⁷⁸⁵,Xu Binyu¹²³⁴⁵,Liu Xiaoming¹²³⁴⁵^ORCID,He Yabing⁶⁷⁸⁵^ORCID,He Yi⁹¹⁰⁴⁵

Affiliation:

1. College of Biological

2. Chemical Sciences and Engineering

3. Jiaxing University

4. Jiaxing 314001

5. China

6. College of Chemistry and Life Sciences

7. Zhejiang Normal University

8. Jinhua 321004

9. Department of Urology

10. Jiaxing First Hospital

Abstract

The diiron(ii) complexes liberated CO in a variety of solvents and the CO-releasing pathway was solvent-dependent. In less polar solvents, the CO-release went through a triiron intermediate. Cytotoxicity of the complexes varied with the halide and the thiolate.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Zhejiang Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C8DT03982H

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