Catalyst-free C(sp<sup>3</sup>)–H functionalization of methyl azaarenes with heteroaromatic trifluoromethyl ketone hydrates: “all-water” synthesis of α-trifluoromethyl tertiary alcohols-Reference-Cited by-同舟云学术

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Catalyst-free C(sp³)–H functionalization of methyl azaarenes with heteroaromatic trifluoromethyl ketone hydrates: “all-water” synthesis of α-trifluoromethyl tertiary alcohols

Published:2023 Issue:20 Volume:21 Page:4304-4308
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Wang Wei¹,Qin Zhaoliang¹,Zhang Xinhui¹,Zhao Wanxiang¹^ORCID,Yang Wen¹^ORCID

Affiliation:

1. Advanced Catalytic Engineering Research Center of the Ministry of Education, College of Chemistry and Chemical Engineering, Hunan University, Changsha, Hunan 410082, P. R. China

Abstract

An efficient catalyst-free C(sp3)–H functionalization of methyl azaarenes with heteroaromatic trifluoromethyl ketone hydrates in neat water for the synthesis of α-trifluoromethyl tertiary alcohols has been developed.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/OB/D3OB00566F

Reference51 articles.

1. P.Ball , H2O: A Biography of Water , Weidenfeld and Nicolson , London , 1999

2. Water: From Clusters to the Bulk

3. Water as a Biomolecule

4. P. A.Grieco , Organic Synthesis in Water , Blackie , London , 1998

5. Organic Synthesis “On Water”

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