Double hydrophosphination of alkynes promoted by rhodium: the key role of an N-heterocyclic carbene ligand-Reference-Cited by-同舟云学术

Double hydrophosphination of alkynes promoted by rhodium: the key role of an N-heterocyclic carbene ligand

Published:2016 Issue:32 Volume:52 Page:5554-5557
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Di Giuseppe Andrea¹²³⁴,De Luca Roberto¹²³⁴⁵,Castarlenas Ricardo¹²³⁴⁵,Pérez-Torrente Jesús J.¹²³⁴^ORCID,Crucianelli Marcello⁵⁶⁷⁸,Oro Luis A.¹²³⁴⁹

Affiliation:

1. Departamento de Química Inorgánica

2. Instituto de Síntesis Química y Catálisis Homogénea (ISQCH) Universidad de Zaragoza–CSIC

3. 50009 Zaragoza

4. Spain

5. Dipartimento di Scienze Fisiche e Chimiche

6. Università dell'Aquila

7. I-67100 Coppito

8. Italy

9. Center for Refining and Petrochemicals

Abstract

The stereoelectronic properties of the NHC ligand make possible the rhodium-catalysed double hydrophosphination of alkynes avoiding the catalyst deactivation by the diphosphine product.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CC/C5CC09156J

Reference46 articles.

1. Catalytic Asymmetric Synthesis of Chiral Phosphanes

2. Catalytic Enantioselective Hydrophosphonylation of Aldehydes and Imines

3. 1-Alkynylphosphines and Their Derivatives as Key Starting Materials in Creating New Phosphines

4. Phosphinate Chemistry in the 21st Century: A Viable Alternative to the Use of Phosphorus Trichloride in Organophosphorus Synthesis.

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