Ambiphilicity of a mononuclear cobalt(iii) superoxo complex-Reference-Cited by-同舟云学术

Ambiphilicity of a mononuclear cobalt(iii) superoxo complex

Published:2020 Issue:94 Volume:56 Page:14821-14824
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Chen Ting-Yi¹²³⁴⁵,Ho Po-Hsun¹²³⁴,Spyra Can-Jerome⁵⁶⁷⁸,Meyer Franc⁵⁶⁷⁸^ORCID,Bill Eckhard⁹¹⁰⁸^ORCID,Ye Shengfa¹¹¹²¹³¹⁴¹⁵^ORCID,Lee Way-Zen¹²³⁴¹⁶^ORCID

Affiliation:

1. Department of Chemistry

2. National Taiwan Normal University

3. Taipei 11677

4. Taiwan

5. Universität Göttingen

6. Institut für Anorganische Chemie

7. D-37077 Göttingen

8. Germany

9. Max-Planck-Institut für Chemische Energiekonversion

10. Mülheim an der Ruhr D-45470

11. State Key Laboratory of Catalysis

12. Dalian Institute of Chemical Physics

13. Chinese Academy of Sciences

14. Dalian 116023

15. China

16. Department of Medicinal and Applied Chemistry

Abstract

Addition of HOTf to a mixture of Co^III(BDPP)(O₂˙) (1) and Cp*₂Fe produced H₂O₂ in high yield implying formation of Co^III(BDPP)(OOH) (3), and reaction of Sc(OTf)₃ with the same mixture gave a peroxo-bridged Co^III/Sc^III5.

Funder

Ministry of Science and Technology, Taiwan

Max-Planck-Gesellschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CC/D0CC05337F

Reference46 articles.

1. Versatility of biological non-heme Fe(II) centers in oxygen activation reactions

2. Dioxygen Activation at Mononuclear Nonheme Iron Active Sites: Enzymes, Models, and Intermediates

3. Dioxygen Activation by Nonheme Diiron Enzymes: Diverse Dioxygen Adducts, High-Valent Intermediates, and Related Model Complexes

4. Copper–Oxygen Complexes Revisited: Structures, Spectroscopy, and Reactivity

5. Status of Reactive Non-Heme Metal–Oxygen Intermediates in Chemical and Enzymatic Reactions

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