Aluminium–ligand cooperation promotes selective dehydrogenation of formic acid to H2 and CO2-Reference-Cited by-同舟云学术

Aluminium–ligand cooperation promotes selective dehydrogenation of formic acid to H2 and CO2

Published:2014 Issue:7 Volume:5 Page:2771-2777
ISSN:2041-6520
Container-title:Chem. Sci.
language:en
Short-container-title:Chem. Sci.

Author:

Myers T. W.¹²³,Berben L. A.¹²³

Affiliation:

1. Department of Chemistry

2. University of California Davis

3. , USA

Abstract

Selective conversion of formic acid to H₂ and CO₂ is catalysed by a molecular aluminum complex. Metal–ligand cooperative interactions stabilize a transition state for an outer-sphere β-hydride abstraction mechanism for catalysis.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/SC/C4SC01035C

Reference51 articles.

1. Group 13 Chemistry III Industrial Applications, ed. H. W. Roesky and D. A. Atwood, Springer, Berlin, 2003

2. P. H. M. Budzelaar and G.Talarico, Insertion and β-Hydride Transfer at Aluminium, in Group 13 Chemistry III Industrial Applications, ed. H. W. Roesky and D. A. Atwood, Springer, Berlin, 2003, pp. 141–167

3. Aluminium-organische Synthese im Bereich olefinischer Kohlenwasserstoffe

4. Quininone1

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