Superhalogens as building blocks of a new series of superacids
Author:
Affiliation:
1. Department of Physics
2. University of Lucknow
3. Lucknow
4. India
Abstract
A new series of superacids by the protonation of BnH3n+1− superhalogen anions has been proposed. The resulting BnH3n+2 species behave as superacids for n ≥ 2 due to their smaller free energy of deprotonation than that of H2SO4. These BnH3n+2 superacids do not require Brønsted/Lewis acid components.
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2017/NJ/C7NJ00129K
Reference43 articles.
1. DVM-Xα calculations on the ionization potentials of MXk+1− complex anions and the electron affinities of MXk+1 “superhalogens”
2. The electronic structure of the 3dand 4dmetal hexafluoride anions and the electron affinities of the corresponding neutrals
3. A theoretical study on the structure and stability of the PFn and PFn− series n=1–6
4. Adiabatic electron affinities of small superhalogens: LiF2, LiCl2, NaF2, and NaCl2
5. First experimental photoelectron spectra of superhalogens and their theoretical interpretations
Cited by 27 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献
1. [NH4+][BxH3x+1–] (x = 1–5): Role of Polynuclear Superhalogens in High-Capacity Hydrogen Storage;Inorganic Chemistry;2024-07-11
2. Superacidic Properties of Protonated PtFn (n = 1–6) and Their Ability to Form Supersalts: DFT Study;Macromolecular Symposia;2024-02
3. Achieving Accuracy and Economy for Calculating Vertical Detachment Energies of Molecular Anions: A Model Chemistry Composite Methods;ChemPhysChem;2024-01-31
4. Superhalogens inside fullerenes X@C2n (X = BO2, BeF3; 2n = 60, 70);Physical Chemistry Chemical Physics;2024
5. HCF4−n(SO3)n (n=1–4): Designing new series of organic superacids;Modern Physics Letters B;2023-12-06
1.学者识别学者识别
2.学术分析学术分析
3.人才评估人才评估
"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370
www.globalauthorid.com
TOP
Copyright © 2019-2024 北京同舟云网络信息技术有限公司 京公网安备11010802033243号 京ICP备18003416号-3