N-Hydroxybenzimidazole as a structurally modifiable platform for N-oxyl radicals for direct C–H functionalization reactions-Reference-Cited by-同舟云学术

N-Hydroxybenzimidazole as a structurally modifiable platform for N-oxyl radicals for direct C–H functionalization reactions

Published:2020 Issue:22 Volume:11 Page:5772-5778
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Yoshii Tomomi¹²³⁴⁵,Tsuzuki Saori¹²³⁴⁵^ORCID,Sakurai Shunya¹²³⁴⁵^ORCID,Sakamoto Ryu¹²³⁴⁵^ORCID,Jiang Julong⁶⁷⁸⁹¹⁰^ORCID,Hatanaka Miho⁶⁷⁸⁹¹⁰^ORCID,Matsumoto Akira¹¹³¹²⁵^ORCID,Maruoka Keiji¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Graduate School of Science

3. Kyoto University

4. Kyoto 606-8502

5. Japan

6. Institute for Research Initiatives

7. Division for Research Strategy

8. Graduate School of Materials Science

9. Data Science Center

10. Nara Institute of Science and Technology

11. Graduate School of Pharmaceutical Sciences

12. Kyoto 606-8501

Abstract

A novel class of N-oxy radicals based on flexibly modifiable N-hydroxybenzimidazole skeleton was designed and applied to C–H functionalization reactions.

Funder

Japan Society for the Promotion of Science

Kyoto University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC02134B

Reference90 articles.

1. Transition-Metal-Catalyzed Selective Functionalization of C(sp3 )−H Bonds in Natural Products

2. Transient Directing Groups for Transformative C–H Activation by Synergistic Metal Catalysis