Supramolecular catalysis in the methylation of meta-phenylene ethynylene foldamer containing N,N-dimethylaminopyridine-Reference-Cited by-同舟云学术

Supramolecular catalysis in the methylation of meta-phenylene ethynylene foldamer containing N,N-dimethylaminopyridine

Published:2017 Issue:23 Volume:7 Page:14046-14052
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Xu Lina¹²³⁴⁵^ORCID,Fang Guoyong¹²³⁴⁵^ORCID,Li Shuhua⁶⁷⁸⁹¹⁰

Affiliation:

1. Key Laboratory of Carbon Materials of Zhejiang Province

2. College of Chemistry and Materials Engineering

3. Wenzhou University

4. Wenzhou 325035

5. China

6. Institute of Theoretical and Computational Chemistry

7. Key Laboratory of Mesoscopic Chemistry of Ministry of Education

8. School of Chemistry and Chemical Engineering

9. Nanjing University

10. Nanjing 210093

Abstract

DFT investigations show that the methylation reaction of N,N-dimethylaminopyridine (DMAP)-modified meta-phenylene ethynylene foldamer can be catalyzed by the noncovalent interactions between the foldamer and the methyl sulfonate esters.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/RA/C7RA00710H

Reference35 articles.

1. Electronics using hybrid-molecular and mono-molecular devices

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3. Exploitation of desilylation chemistry in tailor-made functionalization on diverse surfaces

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