Emergence of comparable covalency in isostructural cerium(iv)– and uranium(iv)–carbon multiple bonds-Reference-Cited by-同舟云学术

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Emergence of comparable covalency in isostructural cerium(iv)– and uranium(iv)–carbon multiple bonds

Published:2016 Issue:5 Volume:7 Page:3286-3297
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Gregson Matthew¹²³⁴,Lu Erli¹²³⁴,Tuna Floriana⁵⁶²³⁴,McInnes Eric J. L.⁵⁶²³⁴,Hennig Christoph⁷⁸⁹¹⁰¹¹,Scheinost Andreas C.⁷⁸⁹¹⁰¹¹,McMaster Jonathan¹¹²¹³¹⁴⁴,Lewis William¹¹²¹³¹⁴⁴,Blake Alexander J.¹¹²¹³¹⁴⁴^ORCID,Kerridge Andrew¹⁵¹⁶¹⁷⁴,Liddle Stephen T.¹²³⁴

Affiliation:

1. School of Chemistry

2. The University of Manchester

3. Manchester

4. UK

5. EPSRC National UK EPR Facility

6. School of Chemistry and Photon Science Institute

7. Helmholtz-Zentrum Dresden-Rossendorf

8. Institute of Resource Ecology

9. D-01314 Dresden

10. Germany

11. The Rossendorf Beamline

12. University of Nottingham

13. University Park

14. Nottingham

15. Department of Chemistry

16. Lancaster University

17. Lancaster

Abstract

Against expectations the covalency in a cerium(iv)–carbon multiple bond interaction is essentially as covalent as the uranium(iv) analogue.

Funder

University Of Nottingham

European Research Council

Engineering and Physical Sciences Research Council

Royal Society

European Cooperation in Science and Technology

University Of Manchester

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/SC/C6SC00278A

Reference134 articles.

1. L. Pauling , The Nature of the Chemical Bond, Cornell University Press, Ithaca, New York, 1939

2. S. Cotton , Lanthanide and Actinide Chemistry, John Wiley & Sons Ltd, Chichester, UK, 2006

3. The Importance of Questioning Scientific Assumptions: Some Lessons from f Element Chemistry

4. Trends in Covalency for d- and f-Element Metallocene Dichlorides Identified Using Chlorine K-Edge X-ray Absorption Spectroscopy and Time-Dependent Density Functional Theory

5. Determining Relative f and d Orbital Contributions to M–Cl Covalency in MCl62– (M = Ti, Zr, Hf, U) and UOCl5– Using Cl K-Edge X-ray Absorption Spectroscopy and Time-Dependent Density Functional Theory

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