Reaching strong absorption up to 700 nm with new benzo[g]quinoxaline-based heteroleptic copper(i) complexes for light-harvesting applications

Author:

Bruschi Cecilia1ORCID,Gui Xin2,Fuhr Olaf34ORCID,Klopper Wim23ORCID,Bizzarri Claudia1ORCID

Affiliation:

1. Institute of Organic Chemistry (IOC), Karlsruhe Institute of Technology (KIT), Fritz-Haber-Weg 6, 76137 Karlsruhe, Germany

2. Institute of Physical Chemistry–Theoretical Chemistry, Karlsruhe Institute of Technology (KIT), Fritz-Haber-Weg 2, 76131 Karlsruhe, Germany

3. Institute of Nanotechnology (INT), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

4. Karlsruhe Nano Micro Facility (KNMFi), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

Abstract

Intense absorption of a large portion of the visible light from new heteroleptic phosphine-bearing Cu(i) complexes is possible thanks to the ligand design, rendering them appealing for light-harvesting applications.

Funder

Klaus Tschira Stiftung

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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