Understanding the sigmatropic shifts of cyclopenta-2,4-dien-1-yltrimethylsilane in its Diels

Understanding the sigmatropic shifts of cyclopenta-2,4-dien-1-yltrimethylsilane in its Diels–Alder addition

Published:2021 Issue:8 Volume:19 Page:1732-1737
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Zhang Min¹²³⁴^ORCID,Liang Guangchao¹⁵⁶⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Mississippi State University

3. Mississippi State

4. USA

5. University of Michigan

6. Ann Arbor

Abstract

Investigation on the dynamic processes of 1-(C₅H₅)Si(Me)₃ in its Diels–Alder addition showed that Si(Me)₃ migration is the dominant factor and hydrogen shifts are negligible.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/OB/D0OB02386H

Reference30 articles.

1. Ethynylsilanes. IV. The effect of temperature on the Diels-Alder addition of acetylenic dienophiles to 1-trimethylsilylcyclopentadiene

2. Spektroskopische untersuchungen an organometallischen verbindungen

3. 1,5-Trimethylsilyl migrations in 1-trimethylsilylindene

4. Hydrogen and trimethylsilyl migrations in 5-(trimethylsilyl) cyclopentadiene

5. Fluxional behavior of cyclopentadienyl, methylcyclopentadienyl, and pentamethylcyclopentadienyl compounds of silicon, germanium, and tin

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