Electrochemical control over stoichiometry via cation intercalation into Chevrel-phase sulphides (CuxMo6S8, x = 1

Electrochemical control over stoichiometry via cation intercalation into Chevrel-phase sulphides (Cu_xMo₆S₈, x = 1–3)

Published:2024 Issue:12 Volume:12 Page:7199-7206
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Ritter Kabian A.¹²,Mason Konstantina G.¹,Yew Suxuen³,Perryman Joseph T.⁴^ORCID,Ortiz-Rodríguez Jessica C.¹^ORCID,Singstock Nicholas R.³^ORCID,Wuille Bille Brian A.¹,Musgrave Charles B.³,Velázquez Jesús M.¹²^ORCID

Affiliation:

1. Department of Chemistry, University of California, One Shields Avenue, Davis, California 95616, USA

2. Energy Systems, Energy and Efficiency Institute, University of California, 1605 Tilia St #100, Davis, California 95616, USA

3. Department of Chemical and Biological Engineering, University of Colorado Boulder, Boulder, Colorado 80303, USA

4. Department of Chemical Engineering, Stanford University, 381 North-South Mall, Stauffer II, Stanford, California 94305, USA

Abstract

This work presents a systematic investigation of the electrochemical intercalation of aqueous copper cations into the Chevrel phase (CP) Mo6S8 and its effect on the host's electronic and structural characteristics as a function of stoichiometry.

Funder

Division of Chemistry

Division of Chemical, Bioengineering, Environmental, and Transport Systems

Division of Materials Research

Research Corporation for Science Advancement

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/TA/D3TA07333E

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