A multifunctional covalently linked graphene–MOF hybrid as an effective chemiresistive gas sensor

Author:

Jayaramulu Kolleboyina12ORCID,Esclance DMello Marilyn3ORCID,Kesavan Kamali45ORCID,Schneemann Andreas6ORCID,Otyepka Michal27ORCID,Kment Stepan28,Narayana Chandrabhas49ORCID,Kalidindi Suresh Babu10ORCID,Varma Rajender S.2ORCID,Zboril Radek278ORCID,Fischer Roland A.11ORCID

Affiliation:

1. Department of Chemistry, Indian Institute of Technology Jammu, Jammu & Kashmir, 181221, India

2. Regional Centre of Advanced Technologies and Materials, Czech Advanced Technology and Research Institute, Palacký University Olomouc, Šlechtitelů 27, 783 71 Olomouc, Czech Republic

3. Materials Science and Catalysis Division, Poornaprajna Institute of Scientific Research, Devanahalli, Bengaluru, 562164, India

4. Chemistry and Physics of Materials Unit, Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR), Jakkur, Bangalore, 560064, India

5. Central Characterisation Department, CSIR- Institute of Minerals and Materials Technology, Bhubaneswar, Odisha, India

6. Lehrstuhl für Anorganische Chemie I, Technische Universität Dresden, Bergstr. 66, 01069 Dresden, Germany

7. IT4Innovations, VSB – Technical University of Ostrava, 17. listopadu 2172/15, 708 00 Ostrava-Poruba, Czech Republic

8. Nanotechnology Centre, Centre of Energy and Environmental Technologies, VŠB–Technical University of Ostrava, 17, listopadu 2172/15, 708 00 Ostrava-Poruba, Czech Republic

9. Rajiv Gandhi Centre for Biotechnology Thycaud P.O., Poojappura Thiruananthapuram, India

10. Department of Inorganic and Analytical Chemistry, Andhra University, Visakhapatnam, 530 003, India

11. Chair of Inorganic and Metal-Organic Chemistry, Department of Chemistry and Catalysis Research Centre, Technical University of Munich, 85748 Garching, Germany

Abstract

The covalent linkage of graphene acid (GA) with amine-functionalized UiO-66-NH2via an amide bond. The resultant hybrid GA@UiO-66-NH2 acts as a chemiresistive CO2 sensor wth significant efficiency owing to its unique structural features.

Funder

Science and Engineering Research Board

European Regional Development Fund

Ministerstvo Školství, Mládeže a Tělovýchovy

Grantová Agentura České Republiky

Council of Scientific and Industrial Research, India

Horizon 2020 Framework Programme

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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