Introduction of plumbole to f-element chemistry-Reference-Cited by-同舟云学术

Introduction of plumbole to f-element chemistry

Published:2022 Issue:4 Volume:13 Page:945-954
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Münzfeld Luca¹^ORCID,Sun Xiaofei¹^ORCID,Schlittenhardt Sören²^ORCID,Schoo Christoph¹^ORCID,Hauser Adrian¹^ORCID,Gillhuber Sebastian³,Weigend Florian⁴^ORCID,Ruben Mario²⁵⁶^ORCID,Roesky Peter W.¹^ORCID

Affiliation:

1. Institute of Inorganic Chemistry, Karlsruhe Institute of Technology (KIT), Engesserstraße 15, D-76131 Karlsruhe, Germany

2. Institute of Nanotechnology, Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, D-76344 Eggenstein-Leopoldshafen, Germany

3. Institute of Physical Chemistry, Karlsruhe Institute of Technology (KIT), Engesserstraße 15, D-76131 Karlsruhe, Germany

4. Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Straße 4, D-35032 Marburg, Germany

5. Centre Européen de Science Quantique (CESQ), Institut de Science et d'Ingénierie Supramoléculaires (ISIS, UMR 7006), CNRS-Université de Strasbourg, 8 allée Gaspard Monge BP 70028, 67083 Strasbourg Cedex, France

6. Institute of Quantum Materials and Technologies (IQMT), Karlsruhe Institute of Technology, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

Abstract

f-element sandwich complexes bearing a η5-plumbole ligand are reported. Quantum chemical calculations suggest that this ligand retains its aromaticity upon coordination. The Er complexes show SMM behavior including magnetic hysteresis.

Funder

Deutsche Forschungsgemeinschaft

Karlsruher Institut für Technologie

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D1SC03805B

Reference82 articles.

1. A New Type of Organo-Iron Compound

2. THE STRUCTURE OF IRON BIS-CYCLOPENTADIENYL