On surface chemical reactions of free-base and titanyl porphyrins with r-TiO<sub>2</sub>(110): a unified picture-Reference-Cited by-同舟云学术

On surface chemical reactions of free-base and titanyl porphyrins with r-TiO₂(110): a unified picture

Published:2022 Issue:21 Volume:24 Page:12719-12744
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Schio Luca¹^ORCID,Forrer Daniel²^ORCID,Casarin Maurizio²³^ORCID,Goldoni Andrea⁴^ORCID,Rogero Celia⁵^ORCID,Vittadini Andrea²^ORCID,Floreano Luca¹^ORCID

Affiliation:

1. CNR-IOM, Laboratorio TASC, Basovizza S.S. 14, Km 163.5, I-34149 Trieste, Italy

2. CNR-ICMATE and INSTM, via Marzolo 1, I-35131 Padova, Italy

3. Dipartimento di Scienze Chimiche, Università di Padova, via Marzolo 1, I-35131 Padova, Italy

4. Elettra-Sincrotrone Trieste S.C.p.A., Basovizza SS-14, Km 163.5, 34149 Trieste, Italy

5. Materials Physics Center MPC, Centro de Física de Materiales (CSIC-UPV/EHU) and Donostia International Physics Center (DIPC), E-20018 San Sebastian, Spain

Abstract

Free-base porphyrins on TiO2(110) anchor to Obr rows, where they capture diluted hydrogen underneath and favour outdiffusion of Ti interstitials by self-metalation; Ti metalated species may also capture oxygen from hydroxyl adsorbates on Ti5f rows.

Funder

Ministerio de Ciencia e Innovación

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D2CP01073A

Reference147 articles.

1. Surface chemistry of porphyrins and phthalocyanines

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4. Electronic structure and bonding in metal porphyrins, metal=Fe, Co, Ni, Cu, Zn

5. Co-Tetraphenylporphyrin (co-TPP) in TM-TPP (TM = Fe, Co, Ni, Cu, and Zn) series: a new optical material under DFT

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