Uniaxial magnetic anisotropy of square-planar chromium(ii) complexes revealed by magnetic and HF-EPR studies

Author:

Deng Yi-Fei12345,Han Tian12345,Wang Zhenxing6789,Ouyang Zhongwen6789,Yin Bing101112139,Zheng Zhiping14151617,Krzystek J.18192017,Zheng Yan-Zhen12345

Affiliation:

1. Centre for Applied Chemical Research

2. Frontier Institute of Science and Technology

3. and MOE Key Laboratory for Nonequilibrium Synthesis

4. College of Science

5. Xi'an Jiaotong University

6. Wuhan National High Magnetic Field Centre

7. Huazhong University of Science and Technology

8. Wuhan 430074

9. China

10. MOE Key Laboratory of Synthetic and Natural Functional Molecule Chemistry

11. College of Chemistry and Materials Science

12. Northwest University

13. Xi'an 710069

14. Department of Chemistry and Biochemistry

15. The University of Arizona

16. Tucson Arizona 85721

17. USA

18. National High Magnetic Field Laboratory

19. Florida State University

20. Tallahassee

Abstract

Two chromium(ii) complexes exhibit single-molecule-magnet behavior due to uniaxial magnetic anisotropy revealed by magnetic and HF-EPR studies.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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