Reduction of 1,2,3-trichloropropane (TCP): pathways and mechanisms from computational chemistry calculations

Author:

Torralba-Sanchez Tifany L.1234ORCID,Bylaska Eric J.5674ORCID,Salter-Blanc Alexandra J.834ORCID,Meisenheimer Douglas E.1234ORCID,Lyon Molly A.1234,Tratnyek Paul G.1234ORCID

Affiliation:

1. OHSU-PSU School of Public Health

2. Oregon Health & Science University

3. Portland

4. USA

5. William R. Wiley Environmental Molecular Sciences Laboratory

6. Pacific Northwest National Laboratory

7. Richland

8. Jacobs

Abstract

Lesser halogenated halocarbons such as 1,2,3-trichloropropane (TCP) are persistent under most conditions, but reductive beta-elimination favors complete dechlorination by hydrogenolysis of the allyl chloride intermediate.

Funder

Strategic Environmental Research and Development Program

U.S. Department of Energy

Pacific Northwest National Laboratory

Publisher

Royal Society of Chemistry (RSC)

Subject

Management, Monitoring, Policy and Law,Public Health, Environmental and Occupational Health,Environmental Chemistry,General Medicine

Reference85 articles.

1. California State Water Resources Control Board , Adopting the Proposed Regulations for a 1,2,3-Trichloropropane (1,2,3-TCP) maximum Contaminant Level (MCL) of 5 Parts Per Trillion , https://www.waterboards.ca.gov/drinking_water/certlic/drinkingwater/documents/123-tcp/sbddw17_001/tab12/rs2017_0042.pdf , 2017

2. OEHHA , Public Health Goals for 1,2,3-Trichloropropane in Drinking Water, Office of Environmental Health and Hazard Assesment (OEHHA) , California Environmental Protection Agency , 2009 , https://www.waterboards.ca.gov/drinking_water/certlic/drinkingwater/documents/123-tcp/sbddw17_001/doc.pdf

3. Factors affecting 1,2,3-trichloropropane contamination in groundwater in California

4. DBCP, EDB, and TCP Contamination of Ground Water in Hawaii

5. E. P. Hooker , K. G.Fulcher and H. J.Gibb , Report to the Hawaii Department of Health, Safe Drinking Water Branch, Regarding the Human Health Risks of 1,2,3-Trichloropropane in Tap Water , Tetra Tech , Arlington, VA , 2012 , https://eha-web.doh.hawaii.gov/eha-cma/documents/fd65a6d2-73d1-4d5c-88c6-97a47ba36650

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