A redox-active inorganic crown ether based on a polyoxometalate capsule-Reference-Cited by-同舟云学术

A redox-active inorganic crown ether based on a polyoxometalate capsule

Published:2023 Issue:20 Volume:14 Page:5453-5459
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Tamai Nanako¹,Ogiwara Naoki¹^ORCID,Hayashi Eri²,Kamata Keigo²^ORCID,Misawa Toshiyuki³^ORCID,Ito Takeru³^ORCID,Kojima Tatsuhiro⁴^ORCID,Segado Mireia⁵^ORCID,Petrus Enric⁵^ORCID,Bo Carles⁵⁶^ORCID,Uchida Sayaka¹^ORCID

Affiliation:

1. Department of Basic Science, School of Arts and Sciences, The University of Tokyo, 3-8-1 Komaba, Meguro-ku, Tokyo 153-8902, Japan

2. Laboratory for Materials and Structures, Institute of Innovative Research, Tokyo Institute of Technology, Nagatsuta-cho 4259, Midori-ku, Yokohama 226-8503, Japan

3. Department of Chemistry, School of Science, Tokai University, 4-1-1 Kitakaname, Hiratsuka 259-1292, Japan

4. Department of Chemistry, Graduate School of Science, Osaka Univerisity, 1-1 Machikaneyamacho, Toyonaka, Osaka 560-0043, Japan

5. Institute of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology (BIST), Av. Països Catalans, 16, 43007 Tarragona, Spain

6. Departament de Química Física i Inorgànica, Universitat Rovira i Virgili, Marcel lí Domingo s/n, 43007 Tarragona, Spain

Abstract

The POM capsule functions as a redox-active inorganic crown ether. Specifically, Cs+ions are captured in the crown-ether-like pores {Mo3Fe3O6}, which exist on the surface of the capsule, and electrons are stored in the Mo atoms of the capsule.

Funder

Ministry of Education, Culture, Sports, Science and Technology

Institut Català d'Investigació Química

Generalitat de Catalunya

Japan Society for the Promotion of Science

Centres de Recerca de Catalunya

Ministerio de Ciencia e Innovación

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC01077E

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