Dibenzoberylloles: antiaromatic s-block fluorene analogues

Author:

Tröster Tobias12,Endres Franziska12,Arrowsmith Merle12ORCID,Endres Lukas12ORCID,Fantuzzi Felipe3ORCID,Braunschweig Holger12ORCID

Affiliation:

1. Institute for Inorganic Chemistry, Julius-Maximilians-Universität Würzburg, Am Hubland, Würzburg 97074, Germany

2. Institute for Sustainable Chemistry & Catalysis with Boron, Julius-Maximilians-Universität Würzburg, Am Hubland, Würzburg 97074, Germany

3. School of Physical Sciences, Ingram Building, University of Kent, Park Wood Rd, Canterbury, CT2 7NH, UK

Abstract

The first Lewis-base-stabilised dibenzoberylloles are prepared, one of which undergoes a complex but selective thermal conversion to a loosely bound beryllium-alkene π complex and two-electron reduction to an aromatic dianion.

Funder

Deutsche Forschungsgemeinschaft

Fonds der Chemischen Industrie

Alexander von Humboldt-Stiftung

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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