Visible-light-induced [3+2] cycloadditions of donor/donor diazo intermediates with alkenes to achieve (spiro)-pyrazolines and pyrazoles-Reference-Cited by-同舟云学术

Visible-light-induced [3+2] cycloadditions of donor/donor diazo intermediates with alkenes to achieve (spiro)-pyrazolines and pyrazoles

Published:2023 Issue:38 Volume:14 Page:10411-10419
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Zhang Yu¹^ORCID,Li Yanchuan²³,Ni Shao-Fei⁴,Li Jin-Peng⁴,Xia Dingding¹,Han Xinyu¹³,Lin Jingchuan¹³,Wang Jinxin³^ORCID,Das Shoubhik⁵⁶^ORCID,Zhang Wei-Dong¹²³⁷

Affiliation:

1. Shanghai Frontiers Science Center for Chinese Medicine Chemical Biology, Institute of Interdisciplinary Integrative Medicine Research, Shanghai University of Traditional Chinese Medicine, No. 1200, Cailun Road, Shanghai 201203, China

2. School of Pharmaceutical Sciences, Zhejiang Chinese Medical University, Hangzhou 310053, China

3. School of Pharmacy, Second Military Medical University, Shanghai 200433, China

4. Department of Chemistry, Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou University, Shantou 515063, China

5. Department of Chemistry, University of Antwerp, Antwerp, Belgium

6. Department of Chemistry, University of Bayreuth, Bayreuth, Germany

7. Institute of Medicinal Plant Development, Chinese Academy of Medical Sciences & Peking Union Medical College, Beijing 100193, China

Abstract

Visible-light-induced [3+2] cycloadditions of donor/donor diazo precursors with alkenes to afford pyrazoles and (spiro)pyrazolines have been reported. Mechanistic and DFT studies suggested the non-covalent interactions promote the reaction.

Funder

Shanghai Education Development Foundation

Shanghai Municipal Education Commission

National Natural Science Foundation of China

National Key Research and Development Program of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC04188C

Reference62 articles.