(E)- and (Z)-stereodefined enol phosphonates derived from β-ketoesters: stereocomplementary synthesis of fully-substituted α,β-unsaturated esters-Reference-Cited by-同舟云学术

(E)- and (Z)-stereodefined enol phosphonates derived from β-ketoesters: stereocomplementary synthesis of fully-substituted α,β-unsaturated esters

Published:2015 Issue:30 Volume:13 Page:8205-8210
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Nakatsuji Hidefumi¹²³⁴⁵,Ashida Yuichiro¹²³⁴⁵,Hori Hiroshi¹²³⁴⁵,Sato Yuka¹²³⁴⁵,Honda Atsushi¹²³⁴⁵,Taira Mayu¹²³⁴⁵,Tanabe Yoo¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. School of Science and Technology

3. Kwansei Gakuin University

4. Sanda

5. Japan

Abstract

A versatile, robust, and stereocomplementary synthesis of fully-substituted (E)- and (Z)-stereodefined α,β-unsaturated esters 3 from accessible α-substituted β-ketoesters 1via (E)- and (Z)-enol phosphonates was achieved.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/OB/C5OB01097G

Reference50 articles.

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