Real-time observation of the Woodward–Hoffmann rule for 1,3-cyclohexadiene by femtosecond soft X-ray transient absorption-Reference-Cited by-同舟云学术

Real-time observation of the Woodward–Hoffmann rule for 1,3-cyclohexadiene by femtosecond soft X-ray transient absorption

Published:2023 Issue:12 Volume:25 Page:8497-8506
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Sekikawa Taro¹^ORCID,Saito Nariyuki²,Kurimoto Yutaro¹,Ishii Nobuhisa³,Mizuno Tomoya²^ORCID,Kanai Teruto²,Itatani Jiro²,Saita Kenichiro⁴^ORCID,Taketsugu Tetsuya⁴⁵

Affiliation:

1. Department of Applied Physics, Faculty of Engineering, Hokkaido University, Sapporo 060-8628, Japan

2. Institute for Solid State Physics, University of Tokyo, Kashiwa 277-8581, Japan

3. Kansai Photon Science Institute, National Institutes for Quantum and Radiological Science and Technology, Kizugawa 619-0215, Japan

4. Department of Chemistry, Faculty of Science, Hokkaido University, Sapporo 060-0810, Japan

5. Institute for Chemical Reaction Design and Discovery (WPI-ICReDD), Hokkaido University, Sapporo 001-0021, Japan

Abstract

The stereochemistry of pericyclic reactions is explained by orbital symmetry conservation, referred to as the Woodward–Hoffmann (WH) rule.

Funder

Core Research for Evolutional Science and Technology

Ministry of Education, Culture, Sports, Science and Technology

Japan Society for the Promotion of Science

Precursory Research for Embryonic Science and Technology

Hokkaido University

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CP/D2CP05268G

Reference47 articles.

1. Biosynthetic and Biomimetic Electrocyclizations

2. The Ultrafast Pathway of Photon-Induced Electrocyclic Ring-Opening Reactions: The Case of 1,3-Cyclohexadiene

3. Ultrafast polyene dynamics: the ring opening of 1,3-cyclohexadiene derivatives

4. Stereoselective photochemical electrocyclic valence isomerizations of .alpha.-phellandrene conformational isomers

5. The Conservation of Orbital Symmetry

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