Conformational preferences induced by cyclization in orbitides: a vibrational CD study

Author:

Yokomichi Maria A. S.1,Silva Hanyeny R. L.2,Brandao Lorenza E. V. N.3,Vicente Eduardo F.3,Batista Jr. Joao M.1ORCID

Affiliation:

1. Institute of Science and Technology, Federal University of Sao Paulo (Unifesp), Rua Talim 330, Sao Jose dos Campos, SP 12231-280, Brazil

2. Sao Paulo State University (Unesp), School of Agricultural and Veterinarian Sciences, Via de Acesso Professor Paulo Donato Castelane Castellane S/N, Jaboticabal, SP 14884-900, Brazil

3. Sao Paulo State University (Unesp), School of Sciences and Engineering, Rua Domingos da Costa Lopes, 780, Tupa, SP 17602-496, Brazil

Abstract

Vibrational CD and DFT calculations reveal solution-state conformational preferences of orbitides following cyclization.

Funder

Fundação de Amparo à Pesquisa do Estado de São Paulo

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

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