Conformationally enforced planarization of bis[1]benzothieno[1,4]thiazines: a rational design of redox-active fluorophores with increased radical cation stability-Reference-Cited by-同舟云学术

Conformationally enforced planarization of bis[1]benzothieno[1,4]thiazines: a rational design of redox-active fluorophores with increased radical cation stability

Published:2024 Issue: Volume: Page:
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Hauer Simone T.¹,Kuhn Patrick¹,Pütz J. Maurice²,Reiss Guido J.²,Sorge Lukas P.³,Ganter Christian²^ORCID,Heinze Katja³^ORCID,Müller Thomas J. J.¹^ORCID

Affiliation:

1. Institut für Organische Chemie und Makromolekulare Chemie, Heinrich-Heine-Universität Düsseldorf, Universitätsstraße 1, D-40225 Düsseldorf, Germany

2. Institut für Anorganische Chemie und Strukturchemie, Heinrich-Heine-Universität Düsseldorf, Universitätsstraße 1, D-40225 Düsseldorf, Germany

3. Institut für Chemie, Johannes-Gutenberg-Universität Mainz, Duesbergweg 10-14, D-55128 Mainz, Germany

Abstract

Rational design results in conformationally restricted bis[1]benzothieno[1,4]thiazines, being antiaromatic in the crystal with staircase-like packing. BBTTs form stable radical cations at low potentials and are strongly luminescent.

Funder

Jürgen Manchot Stiftung

Fonds der Chemischen Industrie

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/QO/D4QO01155D

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