Chiral phosphoric acid-catalyzed asymmetric C(sp3)–H functionalization of biomass-derived 2,5-dimethylfuran via two sequential Cope-type rearrangements-Reference-Cited by-同舟云学术

Chiral phosphoric acid-catalyzed asymmetric C(sp3)–H functionalization of biomass-derived 2,5-dimethylfuran via two sequential Cope-type rearrangements

Published:2019 Issue:8 Volume:6 Page:1162-1167
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Xu Lubin¹²³⁴,Chen Haohua⁵⁶⁷⁴,Liu Jian¹²³⁴,Zhou Lan¹²³⁴,Liu Qing⁸⁹¹⁰⁴,Lan Yu⁵⁶⁷⁴¹¹^ORCID,Xiao Jian¹²³⁴¹²^ORCID

Affiliation:

1. College of Chemistry and Pharmaceutical Sciences

2. Qingdao Agricultural University

3. Qingdao

4. China

5. School of Chemistry and Chemical Engineering

6. Chongqing University

7. Chongqing 400030

8. College of Chemical and Environmental Engineering

9. Shandong University of Science and Technology

10. Qingdao 266590

11. College of Chemistry and Molecular Engineering

12. College of Marine Science and Engineering

Abstract

The first organocatalytic asymmetric C(sp³)–H functionalization of biomass-derived 2,5-dimethylfuran with alcohols to afford enantioenriched furan-derived 3,3′-disubstituted oxindoles in high enantioselectivity.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Shandong Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/QO/C8QO01375F

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1. Carbon-Increasing Catalytic Strategies for Upgrading Biomass into Energy-Intensive Fuels and Chemicals

2. Sustainable Routes for the Synthesis of Renewable Heteroatom-Containing Chemicals