Acid–base responsive molecular switching of a [2]rotaxane incorporating two different stations in an axle component

Author:

Yamane Risa1,Asai Yuki1,Takiguchi Nanami1,Okamoto Ayuna1,Kawano Shintaro2ORCID,Tokunaga Yuji3ORCID,Shizuma Motohiro2ORCID,Muraoka Masahiro1ORCID

Affiliation:

1. Department of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology, Asahi-ku, Osaka 535-8585, Japan

2. Osaka Research Institute of Industrial Science and Technology, Joto-ku, Osaka 536-8553, Japan

3. Department of Materials Science and Engineering, Faculty of Engineering, University of Fukui, Bunkyo, Fukui 910-8507, Japan

Abstract

To design new types of rotaxanes for pH-driven molecular switches, we synthesized a [2]rotaxane with a non-symmetric axial molecule with two different stations. This rotaxane acts as a molecular switch upon application of external acid/base stimuli.

Publisher

Royal Society of Chemistry (RSC)

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