Insights into the chiral sulfide/selenide-catalyzed electrophilic carbothiolation of alkynes: mechanism and origin of axial chirality-Reference-Cited by-同舟云学术

Insights into the chiral sulfide/selenide-catalyzed electrophilic carbothiolation of alkynes: mechanism and origin of axial chirality

Published:2021 Issue:9 Volume:8 Page:1983-1990
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Zhang Qiao-Yu¹²³⁴⁵,Li Shi-Jun¹²³⁴⁵^ORCID,Wang Yang⁶⁷⁸⁹^ORCID,Song Jinshuai¹²³⁴⁵^ORCID,Lan Yu¹²³⁴⁵,Wei Donghui¹²³⁴⁵^ORCID

Affiliation:

1. College of Chemistry

2. and Institute of Green Catalysis

3. Zhengzhou University

4. Zhengzhou 450001

5. P. R. China

6. Department of Material and Chemical Engineering

7. Zhengzhou University of Light Industry

8. Zhengzhou 450002

9. P.R. China

Abstract

The FMO overlap mode, ELF, and AIM analyses along the formation process of thiiranium ion intermediate have been performed for the first time to explore the nature of the electronic structural changes and origin of stereoselectivity.

Funder

National Natural Science Foundation of China

Higher Education Discipline Innovation Project

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/QO/D1QO00036E

Reference49 articles.

1. The Challenge of Atropisomerism in Drug Discovery

2. Unprecedented Selectivity via Electronic Substrate Recognition in the 1,4-Addition to Cyclic Olefins Using a Chiral Disulfoxide Rhodium Catalyst

3. Developments in Chiral Binaphthyl‐Derived Brønsted/Lewis Acids and Hydrogen‐Bond‐Donor Organocatalysis

4. Highly Enantioselective Pd-Catalyzed Allylic Alkylation of Indoles Using Sulfur-MOP Ligand

5. Enantioselective Synthesis of Atropisomers with Multiple Stereogenic Axes

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