Wasted photons: photogeneration yield and charge carrier collection efficiency of hematite photoanodes for photoelectrochemical water splitting

Author:

Piekner Yifat1234ORCID,Ellis David S.5234ORCID,Grave Daniel A.52346ORCID,Tsyganok Anton5234ORCID,Rothschild Avner12345ORCID

Affiliation:

1. The Nancy & Stephen Grand Technion Energy Program (GTEP)

2. Technion – Israel Institute of Technology

3. Haifa 3200002

4. Israel

5. Department of Materials Science and Engineering

6. Department of Materials Engineering and Ilse Katz Institute for Nanoscale Science and Technology

Abstract

A comprehensive method for extraction of the wavelength-dependent fraction of absorbed photons that generate electron–hole pairs and the spatial charge carrier collection efficiency is presented and applied for a thin film hematite photoanode.

Funder

Israel Science Foundation

Ministry of Science and Technology, Israel

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

Reference53 articles.

1. Detailed Balance Limit of Efficiency of p‐n Junction Solar Cells

2. B. Fromme , d–d Excitations on Transition-Metal Oxides , Springer Tracts in Modern Physics, Springer , vol. 170, 2001

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