Mono- and polynuclear Ag(i) complexes of N-functionalized bis(diphenylphosphino)amine DPPA-type ligands: synthesis, solid-state structures and reactivity-Reference-Cited by-同舟云学术

Mono- and polynuclear Ag(i) complexes of N-functionalized bis(diphenylphosphino)amine DPPA-type ligands: synthesis, solid-state structures and reactivity

Published:2017 Issue:17 Volume:46 Page:5571-5586
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Ghisolfi Alessio¹²³⁴⁵,Fliedel Christophe⁶⁷⁸⁹^ORCID,de Frémont Pierre¹²³¹⁰¹¹^ORCID,Braunstein Pierre¹²³⁴⁵^ORCID

Affiliation:

1. Université de Strasbourg

2. CNRS

3. CHIMIE UMR 7177

4. Laboratoire de Chimie de Coordination

5. 67081 Strasbourg

6. Laboratoire de Chimie de Coordination (LCC)

7. CNRS – UPR 8241

8. F-31077 Toulouse Cedex 4

9. France

10. Equipe de Synthèse

11. Réactivité et Catalyse Organométallique

Abstract

DPPA-type ligands (Ph₂P)₂N(p-Z)C₆H₄ (Z = H, SMe, OMe) led to Ag(i) complexes of various nuclearities and an unexpected influence of the para-substituent Z is observed, including for CH₂Cl₂ activation.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C6DT04755F

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