An isoelectronic NO dioxygenase reaction using a nonheme iron(iii)-peroxo complex and nitrosonium ion

Author:

Yokoyama Atsutoshi1234,Han Jung Eun1234,Karlin Kenneth D.567,Nam Wonwoo1234

Affiliation:

1. Department of Chemistry and Nano Science

2. Department of Bioinspired Science

3. Ewha Womans University

4. Seoul 120-750, Korea

5. Department of Chemistry

6. The Johns Hopkins University

7. Baltimore, USA

Abstract

Reaction of a nonheme iron(iii)-peroxo complex, [FeIII(14-TMC)(O2)]+, with NO+ affords an iron(iv)-oxo complex, [FeIV(14-TMC)(O)]2+, and nitrogen dioxide (NO2), followed by conversion to the nitrato complex, [FeIII(14-TMC)(NO3)(F)]+.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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