Tungsten–niobium oxide bronzes: a bulk and surface structural study

Author:

Delgado Daniel12345ORCID,Concepción Patricia1234,Trunschke Annette5678,López Nieto Jose M.1234ORCID

Affiliation:

1. Instituto de Tecnología Química

2. Universitat Politècnica de València-Consejo Superior de Investigaciones Científicas

3. 46022 Valencia

4. Spain

5. Department of Inorganic Chemistry

6. Fritz-Haber-Institute of the Max-Planck-Gesellschaft

7. 14195 Berlin

8. Germany

Abstract

The incorporation of Nb in the hexagonal tungsten bronze leads to a loss of long range order in the ab plane of the structure, the stabilization of W5+ species, and an increase in the Lewis nature of surface acid sites.

Funder

Ministerio de Ciencia, Innovación y Universidades

Universitat Politècnica de València

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference60 articles.

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2. Tungsten oxide-based visible light-driven photocatalysts: crystal and electronic structures and strategies for photocatalytic efficiency enhancement

3. Recent Advances in Tungsten-Oxide-Based Materials and Their Applications

4. P. G. Dickens and M. F.Pye , in Intercalation Chemistry , ed. M. S. Whittingham and A. J. Jacobson , Academic Press , 1982 , pp. 539–561

5. The crystal chemistry of the higher tungsten oxides

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