Characterization of the alkali metal oxalates (MC2O4−) and their formation by CO2 reduction via the alkali metal carbonites (MCO2−)

Author:

Jestilä Joakim S.1234ORCID,Denton Joanna K.567ORCID,Perez Evan H.567,Khuu Thien567ORCID,Aprà Edoardo89107ORCID,Xantheas Sotiris S.11912713ORCID,Johnson Mark A.567ORCID,Uggerud Einar1234ORCID

Affiliation:

1. Department of Chemistry and Hylleraas Centre for Quantum Molecular Sciences

2. University of Oslo

3. Blindern

4. Norway

5. Sterling Chemistry Laboratory, Yale University

6. New Haven

7. USA

8. Environmental Molecular Sciences Laboratory

9. Pacific Northwest National Laboratory

10. Richland

11. Advanced Computing, Mathematics and Data Division

12. MS K1-83, Richland

13. Department of Chemistry

Abstract

The reduction of carbon dioxide to oxalate has been studied by experimental Collisionally Induced Dissociation (CID) and vibrational characterization of the alkali metal oxalates, supplemented by theoretical electronic structure calculations.

Funder

Basic Energy Sciences

Air Force Office of Scientific Research

Norges Forskningsråd

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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