Mutual functionalization of dinitrogen and methane mediated by heteronuclear metal cluster anions CoTaC<sub>2</sub><sup>−</sup>-Reference-Cited by-同舟云学术

Mutual functionalization of dinitrogen and methane mediated by heteronuclear metal cluster anions CoTaC₂⁻

Published:2022 Issue:32 Volume:13 Page:9366-9372
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Mou Li-Hui¹²,Li Yao³²,Wei Gong-Ping¹²,Li Zi-Yu¹²,Liu Qing-Yu¹²,Chen Hui³²^ORCID,He Sheng-Gui¹²^ORCID

Affiliation:

1. State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China

2. Beijing National Laboratory for Molecular Sciences and CAS Research/Education Center of Excellence in Molecular Sciences, Beijing 100190, P. R. China

3. CAS Key Laboratory of Photochemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China

Abstract

A possible N–C bond formation directly from N2 and CH4 mediated by heteronuclear metal cluster anions CoTaC2− at room temperature was identified.

Funder

K. C. Wong Education Foundation

Youth Innovation Promotion Association of the Chinese Academy of Sciences

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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